Multilayered films composed by CdSe Nanocrystals (NCs) interlinked by ethylene-1,2-bis(dithiocarbamate) or adipate anions were prepared on ITO glass via layer-by-layer alternation. The films were analyzed by UV-vis, TEM, Photoluminescence (PL) emission and Pump-Probe spectroscopy. While the PL emission of the two samples present no differences, femtosecond Pumpprobe experiments reveal an higher charge generation efficiency in bis(dithiocarbamate) based films than in dicarboxylate ones.

Photo-Physical Behaviour of CdSe Nanocrystals/Bis(dithiocarbamate) Linker Multilayered Hybrid Systems

Vercelli B;Angella G;Virgili T;Pasini M
2015

Abstract

Multilayered films composed by CdSe Nanocrystals (NCs) interlinked by ethylene-1,2-bis(dithiocarbamate) or adipate anions were prepared on ITO glass via layer-by-layer alternation. The films were analyzed by UV-vis, TEM, Photoluminescence (PL) emission and Pump-Probe spectroscopy. While the PL emission of the two samples present no differences, femtosecond Pumpprobe experiments reveal an higher charge generation efficiency in bis(dithiocarbamate) based films than in dicarboxylate ones.
2015
Istituto di Chimica della Materia Condensata e di Tecnologie per l'Energia - ICMATE
Istituto di fotonica e nanotecnologie - IFN
Istituto per lo Studio delle Macromolecole - ISMAC - Sede Milano
CdSe nanocrystals
Hybrid systems
Photoluminescence
Pump-Probe spectroscopy
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Descrizione: Photo-physical behaviour of cdse nanocrystals/bis(dithiocarbamate) linker multilayered hybrid systems
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/267267
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