Cyclophosphazenes (CyP) containing a crown ether and an ?-amino acid unit have been prepared starting from diphosphaza[16]crown-6 (PNP16C6). Nucleophilic substitution of one (or both) residual ansa-chlorine atom(s) of bis-spiro substituted PNP16C6 by ?-arylsulfonamido esters containing a phenolic function leads to the target compounds. These new polyfunctionalized CyP are lariat ethers, potentially useful as starting materials for the preparation of 'pH-controlled active ion carriers' in liquid membranes. © 2011 Elsevier Ltd. All rights reserved.
Selective O-functionalization of phenolic alpha-amino acids with crown ethers bearing cyclophosphazene sub-units
Penso M;Maia A;
2011
Abstract
Cyclophosphazenes (CyP) containing a crown ether and an ?-amino acid unit have been prepared starting from diphosphaza[16]crown-6 (PNP16C6). Nucleophilic substitution of one (or both) residual ansa-chlorine atom(s) of bis-spiro substituted PNP16C6 by ?-arylsulfonamido esters containing a phenolic function leads to the target compounds. These new polyfunctionalized CyP are lariat ethers, potentially useful as starting materials for the preparation of 'pH-controlled active ion carriers' in liquid membranes. © 2011 Elsevier Ltd. All rights reserved.File in questo prodotto:
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