We present a theoretical study of magnetic relaxation of big molecules, Mn12O12, at low temperature, when the relaxation time tau is temperature independent. If the magnetic field h(z) is not too low, tunneling can only take place if energy is exchanged with phonons. Then, 1/tau similar to h(z)(3) for weak h(z). A steeper increase is expected for higher h(z). The effect of a transverse field h, is small. The maximum of tau(h(z)) observed experimentally at h(z) = 0.2 T might be due to tunneling without phonons in low field, with a relaxation rate reduced by hyperfine interactions.
TUNNELING IN MESOSCOPIC MAGNETIC MOLECULES
POLITI P;
1995
Abstract
We present a theoretical study of magnetic relaxation of big molecules, Mn12O12, at low temperature, when the relaxation time tau is temperature independent. If the magnetic field h(z) is not too low, tunneling can only take place if energy is exchanged with phonons. Then, 1/tau similar to h(z)(3) for weak h(z). A steeper increase is expected for higher h(z). The effect of a transverse field h, is small. The maximum of tau(h(z)) observed experimentally at h(z) = 0.2 T might be due to tunneling without phonons in low field, with a relaxation rate reduced by hyperfine interactions.File in questo prodotto:
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