The halogen bonding between structurally different halo-perfluorocarbons (Rf-X, Rf=aliphatic or aromatic perfluorinated residue, X=I, Br, Cl) and heteroatom containing hydrocarbons (HC-D, HC=hydrocarbon residue, D=electron donor heteroatom) results in the formation of Rf-X?D-HC complexes in the liquid phase. This formation strongly affects the 19F NMR spectra of the perfluorinated partners. The ??-CF2X and the ??-CF?CX- values of perfluoroalkyl and aryl derivatives is proven to be a simple, powerful, and versatile tool to rank the tendency of perfluorocarbon and HC modules to be involved in halogen bonding formation.
Perfluorocarbon-hydrocarbon self-assembly: Part 16. 19F NMR study of the halogen bonding between halo-perfluorocarbons and heteroatom containing hydrocarbons
Panzeri Walter;
2002
Abstract
The halogen bonding between structurally different halo-perfluorocarbons (Rf-X, Rf=aliphatic or aromatic perfluorinated residue, X=I, Br, Cl) and heteroatom containing hydrocarbons (HC-D, HC=hydrocarbon residue, D=electron donor heteroatom) results in the formation of Rf-X?D-HC complexes in the liquid phase. This formation strongly affects the 19F NMR spectra of the perfluorinated partners. The ??-CF2X and the ??-CF?CX- values of perfluoroalkyl and aryl derivatives is proven to be a simple, powerful, and versatile tool to rank the tendency of perfluorocarbon and HC modules to be involved in halogen bonding formation.File in questo prodotto:
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