The rotational spectra of normal and O-d species of the most stable conformer of chiral 1-(4-fluorophenyl)-1-ethanol have been measured by free-jet absorption millimeter-wave spectroscopy. The observed species is stabilized by an O-H-pi interaction and it is at least 1 kcal mol(-1) more stable than the remaining conformers.
Conformational preferences of chiral molecules: free-jet rotational spectrum of 1-(4-fluorophenyl)-1-ethanol
Mauro Satta;
2008
Abstract
The rotational spectra of normal and O-d species of the most stable conformer of chiral 1-(4-fluorophenyl)-1-ethanol have been measured by free-jet absorption millimeter-wave spectroscopy. The observed species is stabilized by an O-H-pi interaction and it is at least 1 kcal mol(-1) more stable than the remaining conformers.File in questo prodotto:
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