A number of general trends are known to occur in systems displaying secondary processes in glasses and glass formers. Universal features can be identified as components of large and small cooperativeness whose competition leads to excess wings or apart peaks in the susceptibility spectrum. To the aim of understanding such rich and complex phenomenology we analyze the behavior of a model combining two apart glassy components with a tunable different cooperativeness. The model salient feature is, indeed, based on the competition of the energetic contribution of groups of dynamically relevant variables, e.g., density fluctuations, interacting in small and large sets. We investigate how the model is able to reproduce the secondary processes physics without further ad hoc ingredients, displaying known trends and properties under cooling or pressing. (C) 2014 Elsevier B.V. All rights reserved.

A simple spin model for three step relaxation and secondary processes in glass formers

2014

Abstract

A number of general trends are known to occur in systems displaying secondary processes in glasses and glass formers. Universal features can be identified as components of large and small cooperativeness whose competition leads to excess wings or apart peaks in the susceptibility spectrum. To the aim of understanding such rich and complex phenomenology we analyze the behavior of a model combining two apart glassy components with a tunable different cooperativeness. The model salient feature is, indeed, based on the competition of the energetic contribution of groups of dynamically relevant variables, e.g., density fluctuations, interacting in small and large sets. We investigate how the model is able to reproduce the secondary processes physics without further ad hoc ingredients, displaying known trends and properties under cooling or pressing. (C) 2014 Elsevier B.V. All rights reserved.
2014
Istituto per i Processi Chimico-Fisici - IPCF
Istituto dei Sistemi Complessi - ISC
Secondary process
Glass
Mode Coupling Theory
Spin glass
Spherical models
File in questo prodotto:
File Dimensione Formato  
prod_322488-doc_103739.pdf

solo utenti autorizzati

Descrizione: Articolo pubblicato
Tipologia: Versione Editoriale (PDF)
Dimensione 1.12 MB
Formato Adobe PDF
1.12 MB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/280538
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? 5
social impact