A boronic analogue of the archetype matrix alpha-cyano-4-hydroxy-cinnamic acid (CHCA) has been synthesised providing a new "reactive matrix'' that possesses molecular recognition properties. This matrix selectively recognizes vic-diols, alpha-hydroxyacids, aminols and first allowed the detection of anions as fluoride (unaffordable by usual matrices).
Boronic acid chemistry in MALDI MS: a step forward in designing a reactive matrix with molecular recognition capabilities
Nacci A;
2014
Abstract
A boronic analogue of the archetype matrix alpha-cyano-4-hydroxy-cinnamic acid (CHCA) has been synthesised providing a new "reactive matrix'' that possesses molecular recognition properties. This matrix selectively recognizes vic-diols, alpha-hydroxyacids, aminols and first allowed the detection of anions as fluoride (unaffordable by usual matrices).File in questo prodotto:
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