The reaction of some halogenoarene tricarbonylchromium complexes, e.g., I (R = F), with NH2COCF3/NaH and NH2P(O)(OCH2Ph)2/NaH affords variously substituted complexed aniline derivs., e.g., I [R = NHCOCF3, NHP(O)(OCH2Ph)2], in 30-80% yields and under mild conditions.
Aromatic nucleophilic substitution of haloarene tricarbonyl chromium complexes: synthesis of chromium tricarbonyl complexed aniline derivatives
Baldoli Clara;
1992
Abstract
The reaction of some halogenoarene tricarbonylchromium complexes, e.g., I (R = F), with NH2COCF3/NaH and NH2P(O)(OCH2Ph)2/NaH affords variously substituted complexed aniline derivs., e.g., I [R = NHCOCF3, NHP(O)(OCH2Ph)2], in 30-80% yields and under mild conditions.File in questo prodotto:
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