We investigate the slow dynamics of a simple glass former whose interaction potential is the sum of a hard core and a square shoulder repulsion. According to mode coupling theory, the competition between the two repulsive length scales gives rise to a complex dynamic scenario: besides the fluid-glass line, the theory predicts a glass-glass line in the temperature-packing fraction plane with two end points. Interestingly, for critical values of the square-shoulder parameters, such end points can be accessed from the liquid phase. We verify, via extensive numerical simulations, the existence of both points through the observation of an unconventional subdiffusive/logarithmic dynamical behavior. Unexpectedly, we also discover that the simultaneous presence of two end points generates special loci in the state diagram along which the dynamics is identical at all length and time scales.

Multiple glass singularities and isodynamics in a core-softened model for glass-forming systems

Nicoletta Gnan;Francesco Sciortino;Emanuela Zaccarelli
2014

Abstract

We investigate the slow dynamics of a simple glass former whose interaction potential is the sum of a hard core and a square shoulder repulsion. According to mode coupling theory, the competition between the two repulsive length scales gives rise to a complex dynamic scenario: besides the fluid-glass line, the theory predicts a glass-glass line in the temperature-packing fraction plane with two end points. Interestingly, for critical values of the square-shoulder parameters, such end points can be accessed from the liquid phase. We verify, via extensive numerical simulations, the existence of both points through the observation of an unconventional subdiffusive/logarithmic dynamical behavior. Unexpectedly, we also discover that the simultaneous presence of two end points generates special loci in the state diagram along which the dynamics is identical at all length and time scales.
2014
Istituto dei Sistemi Complessi - ISC
Inglese
113
25
5
http://journals.aps.org/prl/abstract/10.1103/PhysRevLett.113.258302
Sì, ma tipo non specificato
multiple glass
coupling theory
dynamical behavior
times scale
Published 18 December 2014. In part supported from Ministero dell'Istruzione, dell'Università e della Ricerca (" Futuro in Ricerca" ANISOFT/RBFR125H0M), G. D., F. S., and E. Z. from EU ITN-234810-COMPLOIDS and M.S. from DFG under FG1394.
5
info:eu-repo/semantics/article
262
Gnan, Nicoletta; Das, Gayatri; Sperl, Matthias; Sciortino, Francesco; Zaccarelli, Emanuela
01 Contributo su Rivista::01.01 Articolo in rivista
restricted
   Physics of Complex Colloids: Equilibrium and Driven
   COMPLOIDS
   FP7
   234810
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/282578
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