Ruthenium(II) complexes of 2,2' : 6',2"-terpyridine have not been widely investigated as photocatalysts; the introduction of electron-withdrawing substituents into the 4'-position of the ligand results in complexes [Ru(Xtpy)2]2+ (Xtpy = Cltpy or MeSO2tpy), which luminesce in fluid solution at room temperature.
LIGAND SUBSTITUTION PATTERNS CONTROL PHOTOPHYSICAL PROPERTIES OF RUTHENIUM(II)-2,2',/6',2''-TERPYRIDINE COMPLEXES - ROOM-TEMPERATURE EMISSION FROM [RU(TPY)2]2+ ANALOGS
ARMAROLI N;
1992
Abstract
Ruthenium(II) complexes of 2,2' : 6',2"-terpyridine have not been widely investigated as photocatalysts; the introduction of electron-withdrawing substituents into the 4'-position of the ligand results in complexes [Ru(Xtpy)2]2+ (Xtpy = Cltpy or MeSO2tpy), which luminesce in fluid solution at room temperature.File in questo prodotto:
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