The high frequency collective dynamics of liquid hydrogen fluoride is studied by inelastic x-ray scattering on the coexistence curve at T = 239 K. The comparison with existing molecular dynamics simulations shows the existence of two active relaxation processes with characteristic time scales in the subpicosecond range. The observed scenario is very similar to that found in liquid water. This suggests that hydrogen bonded liquids behave similarly to other very different systems as simple and glass forming liquids, thus indicating that these two relaxation processes are universal features of the liquid state.

Structural and microscopic relaxation processes in liquid hydrogen fluoride

Angelini R;
2002

Abstract

The high frequency collective dynamics of liquid hydrogen fluoride is studied by inelastic x-ray scattering on the coexistence curve at T = 239 K. The comparison with existing molecular dynamics simulations shows the existence of two active relaxation processes with characteristic time scales in the subpicosecond range. The observed scenario is very similar to that found in liquid water. This suggests that hydrogen bonded liquids behave similarly to other very different systems as simple and glass forming liquids, thus indicating that these two relaxation processes are universal features of the liquid state.
2002
Inelastic X-ray scattering
hydrogen bond
hydrogen fluoride
structural relaxation
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/289855
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