Cu2+ coordination by a tridentate phenanthroline-related derivative (P120) was examined and compared to phenanthroline. Results from X-ray analysis underlined significant increments in the N-Cu bond lengths in Cu(P120)(H2O)SO4 which are counterbalanced by a closer approach of the apical oxygen donors to the metal. These modifications may be related to the different properties observed in physiological environment. (C) 2015 Elsevier B.V. All rights reserved.
Biologically relevant Cu2+ complexes with a tridentate phenanthroline analogue: Structural properties and DNA damage
Bolzati C;
2015
Abstract
Cu2+ coordination by a tridentate phenanthroline-related derivative (P120) was examined and compared to phenanthroline. Results from X-ray analysis underlined significant increments in the N-Cu bond lengths in Cu(P120)(H2O)SO4 which are counterbalanced by a closer approach of the apical oxygen donors to the metal. These modifications may be related to the different properties observed in physiological environment. (C) 2015 Elsevier B.V. All rights reserved.File in questo prodotto:
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Descrizione: Biologically relevant Cu2+ complexes with a tridentate phenanthroline analogue: Structural properties and DNA damage
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