trans-A(2)B-corroles bearing -OCH2CONHR groups at the ortho position of the meso-phenyl substituent undergo self-organization both in the solid state as well as in solution. The lack of additional donor atoms induces sheet formation, but if the pyridine unit is present in the structure, more complex helical forms are formed.
Self-assembling corroles
Ventura Barbara;Barbieri Andrea;
2015
Abstract
trans-A(2)B-corroles bearing -OCH2CONHR groups at the ortho position of the meso-phenyl substituent undergo self-organization both in the solid state as well as in solution. The lack of additional donor atoms induces sheet formation, but if the pyridine unit is present in the structure, more complex helical forms are formed.File in questo prodotto:
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