'Gear-like' rotations of simple C C bonds have been observed in some aziridine methanol derivatives. These restricted rotations have been studied by dynamic and multinuclear magnetic resonance experiments, and the barrier for rotations of Csp(3)-Csp(3) and Csp(3)-Csp(2) bonds have been calculated. The role of an intramolecular hydrogen bond on the stereodynamics has also been demonstrated. (C) 2011 Elsevier Ltd. All rights reserved.
Restricted rotations and stereodynamics of aziridine-2-methanol derivatives
Falcicchio Aurelia;
2011
Abstract
'Gear-like' rotations of simple C C bonds have been observed in some aziridine methanol derivatives. These restricted rotations have been studied by dynamic and multinuclear magnetic resonance experiments, and the barrier for rotations of Csp(3)-Csp(3) and Csp(3)-Csp(2) bonds have been calculated. The role of an intramolecular hydrogen bond on the stereodynamics has also been demonstrated. (C) 2011 Elsevier Ltd. All rights reserved.File in questo prodotto:
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