Stereoselective nucleophilic phosphonylations of alpha-silyloxy aldehydes with TMSDEP proceed with moderate to excellent diastereoselectivity. The sense of asymmetric induction is strongly depending on the presence of bulky trialkyl silyloxy groups.
STEREOSELECTIVE SYNTHESIS OF ALPHA,BETA-DISILYLOXY PHOSPHONATES BY STEREOSELECTIVE PHOSPHONYLATION OF ALPHA-SILYLOXYALDEHYDES
BANDINI E;
1995
Abstract
Stereoselective nucleophilic phosphonylations of alpha-silyloxy aldehydes with TMSDEP proceed with moderate to excellent diastereoselectivity. The sense of asymmetric induction is strongly depending on the presence of bulky trialkyl silyloxy groups.File in questo prodotto:
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