A cathode structure for photon-enhanced thermionic emission was designed for high temperature energy conversion in solar concentrating systems. Surface-hydrogenated diamond is one of the few semiconductors to show negative electron affinity and a work function as low as 1.7 eV if nitrogen-doped, that is connected to a significant thermionic emission at moderate temperatures (up to 800 °C). But diamond is transparent to solar radiation, consequently advanced techniques for preparing an efficient sunlight absorbing diamond are discussed.

Defect Engineering of Diamond Cathodes for High Temperature Solar Cells

A Bellucci;P Calvani;M Girolami;D M Trucchi
2015

Abstract

A cathode structure for photon-enhanced thermionic emission was designed for high temperature energy conversion in solar concentrating systems. Surface-hydrogenated diamond is one of the few semiconductors to show negative electron affinity and a work function as low as 1.7 eV if nitrogen-doped, that is connected to a significant thermionic emission at moderate temperatures (up to 800 °C). But diamond is transparent to solar radiation, consequently advanced techniques for preparing an efficient sunlight absorbing diamond are discussed.
2015
Istituto di Struttura della Materia - ISM - Sede Roma Tor Vergata
978-1-4799-7992-9
CVD Diamond; Solar concentration; Energy conversion; Thermionic emission; Photo-emission
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/296649
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