The vibrational features and molecular structures of complexes formed by a series of uranyl-salophen receptors with simple anions, such as Cl-, H-, and HCOO-, have been investigated in the gas phase. Spectra of the anionic complexes were studied in the (nu) over tilde = 800-1800 cm(-1) range by mass-selective infrared multiple photon dissociation (IRMPD) spectroscopy with a continuously tunable free-electron laser. The gas-phase decarboxylation of the formate adducts produces uranyl-salophen monohydride anions, which have been characterized for the first time and reveal a strong U-H bond, the nature of which has been elucidated theoretically. The spectra are in excellent agreement with the results obtained from high-quality ab initio calculations, which provided the structure and binding features of the anion-receptor complexes.
Anion Recognition by Uranyl-Salophen Derivatives as Probed by Infrared Multiple Photon Dissociation Spectroscopy and Ab Initio Modeling
A Dalla Cort;
2014
Abstract
The vibrational features and molecular structures of complexes formed by a series of uranyl-salophen receptors with simple anions, such as Cl-, H-, and HCOO-, have been investigated in the gas phase. Spectra of the anionic complexes were studied in the (nu) over tilde = 800-1800 cm(-1) range by mass-selective infrared multiple photon dissociation (IRMPD) spectroscopy with a continuously tunable free-electron laser. The gas-phase decarboxylation of the formate adducts produces uranyl-salophen monohydride anions, which have been characterized for the first time and reveal a strong U-H bond, the nature of which has been elucidated theoretically. The spectra are in excellent agreement with the results obtained from high-quality ab initio calculations, which provided the structure and binding features of the anion-receptor complexes.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
