A safe and mild procedure for the synthesis of org. carbonates from alkyl halides and Et4N+ carbonate (TEAC) is described. This method avoids the use of classical toxic and harmful chems. like phosgene and CO and works under very mild reaction conditions. An electrochem.-generated deriv. of CO2 (a cheap and abundant C source) was used as the main reagent (TEAC).
A safe synthesis of symmetrical carbonates from alkyl halides and tetraethylammonium carbonate
2002
Abstract
A safe and mild procedure for the synthesis of org. carbonates from alkyl halides and Et4N+ carbonate (TEAC) is described. This method avoids the use of classical toxic and harmful chems. like phosgene and CO and works under very mild reaction conditions. An electrochem.-generated deriv. of CO2 (a cheap and abundant C source) was used as the main reagent (TEAC).File in questo prodotto:
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