Characterization of p-mercaptobenzoic acid (p-MBA) protected Au-102(p-MBA)(44) nanomolecules has been so far limited by its water-soluble ligand system. In this work we report the first synthesis and isolation of thiolateprotected organosoluble Au-102(SPh-X)(44) nanomolecules via one-phase synthesis. Monodispersity of the nanomolecules was confirmed from matrix-assisted laser desorption ionization mass spectrometry (MALDI-MS), and composition was determined from high-resolution electrospray ionization mass spectrometry (ESI-MS). For the first time we report the electrochemical behavior and temperature-dependent optical spectra of Au-102(SPh)(44). Theoretical simulations on the titled nanomolecules fully validate experimental data and demonstrate the role of electronic conjugation on optical properties.
Organosoluble Au-102(SPh)(44) Nanomolecules: Synthesis, Isolation, Compositional Assignment, Core Conversion, Optical Spectroscopy, Electrochemistry, and Theoretical Analysis
Sementa Luca;Barcaro Giovanni;Fortunelli Alessandro;
2015
Abstract
Characterization of p-mercaptobenzoic acid (p-MBA) protected Au-102(p-MBA)(44) nanomolecules has been so far limited by its water-soluble ligand system. In this work we report the first synthesis and isolation of thiolateprotected organosoluble Au-102(SPh-X)(44) nanomolecules via one-phase synthesis. Monodispersity of the nanomolecules was confirmed from matrix-assisted laser desorption ionization mass spectrometry (MALDI-MS), and composition was determined from high-resolution electrospray ionization mass spectrometry (ESI-MS). For the first time we report the electrochemical behavior and temperature-dependent optical spectra of Au-102(SPh)(44). Theoretical simulations on the titled nanomolecules fully validate experimental data and demonstrate the role of electronic conjugation on optical properties.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
