In coordination chemistry, the nature and strength of the metal-ligand interaction has attracted much interest. Metal-sulfur complexes, in particular in comparison with their oxygen-based analogues, are intriguing as the sulfur atoms are polarized more easily. ....... ..... Metal dithiocarbamates [R2NCS2]lM have been extensively studied by IR and UV-vis. spectroscopy, ESR and to a limited extent XPS and UPS. .....
Spectroscopic and Theoretical Investigations on Pd(II) andPt(II) Dithiocarbamates
Forrer D;Gross S;Casarin M;
2010
Abstract
In coordination chemistry, the nature and strength of the metal-ligand interaction has attracted much interest. Metal-sulfur complexes, in particular in comparison with their oxygen-based analogues, are intriguing as the sulfur atoms are polarized more easily. ....... ..... Metal dithiocarbamates [R2NCS2]lM have been extensively studied by IR and UV-vis. spectroscopy, ESR and to a limited extent XPS and UPS. .....File in questo prodotto:
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Descrizione: Spectroscopic and Theoretical Investigations on Pd(II) andPt(II) Dithiocarbamates
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