A Cu-based organic-inorganic perovskite framework exhibits high-temperature ferroelectricity with strong magnetoelectric effects. Both electric field control of magnetization and magnetic field control of polarization are realized. Theoretical calculations suggest that a new mechanism of hybrid improper ferroelectricity arising from the Jahn-Teller distortions of magnetic metal ions and tilting of the organic cations are responsible for the peculiar multiferroic behaviors.
High-temperature ferroelectricity and strong magnetoelectric effects in a hybrid organic-inorganic perovskite framework
Stroppa A;Barone P;Picozzi S;
2015
Abstract
A Cu-based organic-inorganic perovskite framework exhibits high-temperature ferroelectricity with strong magnetoelectric effects. Both electric field control of magnetization and magnetic field control of polarization are realized. Theoretical calculations suggest that a new mechanism of hybrid improper ferroelectricity arising from the Jahn-Teller distortions of magnetic metal ions and tilting of the organic cations are responsible for the peculiar multiferroic behaviors.File in questo prodotto:
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