We describe a new sol-gel molecular electrode made of a thin layer of organosilica doped with the nitroxyl radical TEMPO (2,2,6,6-tetramethylpiperidine- 1-oxyl) electrodeposited on the surface of an ITO-coated glass and its employment as a selective and versatile oxidation catalyst in the electrochemical conversion of different alcohols to carbonyl compounds. Environmentally friendly water or a water/acetonitrile mixture buffered with bicarbonate is used as solvent. The electrode is highly stable and it can be reused for a prolonged period of time allowing easy separation from the products
Waste-free electrochemical oxidation of alchools in water
Rosaria Ciriminna;Mario Pagliaro
2006
Abstract
We describe a new sol-gel molecular electrode made of a thin layer of organosilica doped with the nitroxyl radical TEMPO (2,2,6,6-tetramethylpiperidine- 1-oxyl) electrodeposited on the surface of an ITO-coated glass and its employment as a selective and versatile oxidation catalyst in the electrochemical conversion of different alcohols to carbonyl compounds. Environmentally friendly water or a water/acetonitrile mixture buffered with bicarbonate is used as solvent. The electrode is highly stable and it can be reused for a prolonged period of time allowing easy separation from the productsFile in questo prodotto:
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