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We used a very simplified electrostatic model based on charge and polarizability of atoms and groups on an organic ligand around a lanthanide ion to predict the near-infrared electronic circular dichroism (NIR ECD) spectra of Yb<sup>3+</sup> (a monoelectronic ion). We tuned our method by using two widely different complexes. The first was the heterobimetallic species CsYb(hfbc)<inf>4</inf> [hfbc=(-)-3-heptafluorobutyrylcamphorate], in which the ligand is a diketonate and, as such, is endowed with a chromophore with strong UV absorption (?-?<sup>*</sup>). Its oxygen atoms define a square antiprism, which provides a symmetric coordination polyhedron. The second system was Yb DOTMA [DOTMA=(1R,4R,7R,10R)-?,??,???,????-tetramethyl-1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid], a chiral Yb analogue of Gd DOTA (DOTA=1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid), in which the ligand lacks relevant electronic transitions and provides a dissymmetric cage. The relative weights of dynamic (ligand polarization) and static contributions to Yb NIR ECD were evaluated, and the spectra appear to have been well predicted by theory through the introduction of a heuristic weight factor. To validate the approach and to confirm the value of the weight factor, we applied it to two other compounds, namely, Na<inf>3</inf>Yb(BINOLate)<inf>3</inf> and Yb(BINOLAM)<inf>3</inf> [BINOLate=2,2?-dihydroxy-1,1?-binaphthyl; BINOLAM=3,3?-bis(diethylaminomethyl)-1-1?-bi-2-naphthol]. Going round in circles: The near-infrared electronic circular dichroism spectra of Yb<sup>3+</sup> are predicted on the basis of a simplified electrostatic model based on the charge and polarizability of atoms and groups on an organic ligand around a lanthanide ion. The relative weights of dynamic and static contributions are evaluated; the spectra appear to be well predicted by theory through the introduction of a heuristic weight factor.
Optical Activity in the Near-IR Region: The ?=980 nm Multiplet of Chiral Yb3+ Complexes
We used a very simplified electrostatic model based on charge and polarizability of atoms and groups on an organic ligand around a lanthanide ion to predict the near-infrared electronic circular dichroism (NIR ECD) spectra of Yb3+ (a monoelectronic ion). We tuned our method by using two widely different complexes. The first was the heterobimetallic species CsYb(hfbc)4 [hfbc=(-)-3-heptafluorobutyrylcamphorate], in which the ligand is a diketonate and, as such, is endowed with a chromophore with strong UV absorption (?-?*). Its oxygen atoms define a square antiprism, which provides a symmetric coordination polyhedron. The second system was Yb DOTMA [DOTMA=(1R,4R,7R,10R)-?,??,???,????-tetramethyl-1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid], a chiral Yb analogue of Gd DOTA (DOTA=1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid), in which the ligand lacks relevant electronic transitions and provides a dissymmetric cage. The relative weights of dynamic (ligand polarization) and static contributions to Yb NIR ECD were evaluated, and the spectra appear to have been well predicted by theory through the introduction of a heuristic weight factor. To validate the approach and to confirm the value of the weight factor, we applied it to two other compounds, namely, Na3Yb(BINOLate)3 and Yb(BINOLAM)3 [BINOLate=2,2?-dihydroxy-1,1?-binaphthyl; BINOLAM=3,3?-bis(diethylaminomethyl)-1-1?-bi-2-naphthol]. Going round in circles: The near-infrared electronic circular dichroism spectra of Yb3+ are predicted on the basis of a simplified electrostatic model based on the charge and polarizability of atoms and groups on an organic ligand around a lanthanide ion. The relative weights of dynamic and static contributions are evaluated; the spectra appear to be well predicted by theory through the introduction of a heuristic weight factor.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/306860
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