The ground state ring puckering splitting of the cyclopentane ring of indan has been precisely determined (Delta E-01 = 22.364(1) MHz) by measuring the very weak mu(c)-type transitions with pulse jet Fourier transform microwave spectroscopy. In addition, the rotational spectra of all C-13 monosubstituted isotopologues have been assigned and measured in natural abundance, leading to an accurate structure of the heavy atoms frame. (C) 2015 Elsevier Inc. All rights reserved.
Ring puckering splitting and structure of indan
2015
Abstract
The ground state ring puckering splitting of the cyclopentane ring of indan has been precisely determined (Delta E-01 = 22.364(1) MHz) by measuring the very weak mu(c)-type transitions with pulse jet Fourier transform microwave spectroscopy. In addition, the rotational spectra of all C-13 monosubstituted isotopologues have been assigned and measured in natural abundance, leading to an accurate structure of the heavy atoms frame. (C) 2015 Elsevier Inc. All rights reserved.File in questo prodotto:
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