The stability of phosphorene is shown to be degraded by water. However, the presence of a small amount of water allows the synthesis of high-quality material in liquid exfoliation of black phosphorus using dimethylsulfoxide as solvent. A phosphorus/water molar ratio between 1.5 and 14 maximizes the quality of the phosphorene flakes and their stability.

The Role of Water in the Preparation and Stabilization of High-Quality Phosphorene Flakes

Caporali M;Ienco A;Heun S;Peruzzini M
2016

Abstract

The stability of phosphorene is shown to be degraded by water. However, the presence of a small amount of water allows the synthesis of high-quality material in liquid exfoliation of black phosphorus using dimethylsulfoxide as solvent. A phosphorus/water molar ratio between 1.5 and 14 maximizes the quality of the phosphorene flakes and their stability.
2016
Istituto di Chimica dei Composti OrganoMetallici - ICCOM -
Istituto Nanoscienze - NANO
black phosphorus
liquid exfoliation
phosphorene
two-dimensional materials
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/310974
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