Novel copolyacrylates containing various molar ratios of 5,10,15-tri[p-(9-methoxy-triethylenoxy)phenyl]-20-(pacryloxyphenyl) porphyrin units in the chains have been synthesized, and their chemical structure was determined by NMR and MALDI-TOF mass spectrometry. Sensing response of the synthesized copolymers has been tested for trifluoroacetic and hydrochloric acids and nitrogen dioxide analytes. The reported sensing data indicate that porphyrin units are interacting with analytes in a reversible fashion.

Synthesis and Characterization of New Copolyacrylates Containing Porphyrin Units as Pendant Groups and Their Use as Sensors

S DATTILO;P MINEO;E SPINA;D VITALINI
2011

Abstract

Novel copolyacrylates containing various molar ratios of 5,10,15-tri[p-(9-methoxy-triethylenoxy)phenyl]-20-(pacryloxyphenyl) porphyrin units in the chains have been synthesized, and their chemical structure was determined by NMR and MALDI-TOF mass spectrometry. Sensing response of the synthesized copolymers has been tested for trifluoroacetic and hydrochloric acids and nitrogen dioxide analytes. The reported sensing data indicate that porphyrin units are interacting with analytes in a reversible fashion.
2011
Istituto per i Polimeri, Compositi e Biomateriali - IPCB
addition polymerization; MALDI; MALDI-TOF massspectrometry; polyacrylates; porphyrin; sensors; UV-vis spectroscopy
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Descrizione: Synthesis and Characterization of New Copolyacrylates ContainingPorphyrin Units as Pendant Groups and Their Use as Sensors
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/311319
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