Silanes and silicon containing compounds have been long since recognized as very important tools in organic synthesis, and their reactions have been the subject of many investigations in recent and less recent years. We give here a survey of the results of our ESR spectroscopic studies of some carbon to oxygen silicon migrations, namely 1,2-silicon shifts in alfa-ketosilanes and 1,3-silicon shifts in the adducts between unsaturated carbonyl compounds and silicon centred radicals.
An ESR approach to some 1,2 and 1,3 carbon to oxygen silicon shifts
Alberti A
1986
Abstract
Silanes and silicon containing compounds have been long since recognized as very important tools in organic synthesis, and their reactions have been the subject of many investigations in recent and less recent years. We give here a survey of the results of our ESR spectroscopic studies of some carbon to oxygen silicon migrations, namely 1,2-silicon shifts in alfa-ketosilanes and 1,3-silicon shifts in the adducts between unsaturated carbonyl compounds and silicon centred radicals.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
