The reactions of indole with nitrosobenzene in the presence of acetic, monochloroacetic, monobromoacetic and trichloroacetic acid afford as the main product a deep-green precipitate, which in a preceding study had been erroneously identified as the aminyl radical of a trimer indole. The identity of the minor products was confirmed. This paper deals with the determination of the correct structure of the compounds contained in the precipitate through a study based on chemical reactions, electrochemical measurements and X-ray analysis.

Oxidative trimerization of indole: On the formation of dications and radical cations by reaction of indole and nitrosobenzene in the presence of acids

Alberti A
2000

Abstract

The reactions of indole with nitrosobenzene in the presence of acetic, monochloroacetic, monobromoacetic and trichloroacetic acid afford as the main product a deep-green precipitate, which in a preceding study had been erroneously identified as the aminyl radical of a trimer indole. The identity of the minor products was confirmed. This paper deals with the determination of the correct structure of the compounds contained in the precipitate through a study based on chemical reactions, electrochemical measurements and X-ray analysis.
2000
Istituto per la Sintesi Organica e la Fotoreattivita' - ISOF
Indole; nitrosobenzene; oxidative trimerization
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/313632
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