Fe(II) hydrido carbonyl complexes supported by PNP pincer ligands based on the 2,6-diaminopyridine scaffold were studied as homogeneous, non-precious-metal-based catalysts for selective formic acid dehydrogenation to hydrogen and carbon dioxide, reaching quantitative yields and high TONs under mild reaction conditions.
Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold
Mellone Irene;Bertini Federica;Peruzzini Maurizio;Gonsalvi Luca
2016
Abstract
Fe(II) hydrido carbonyl complexes supported by PNP pincer ligands based on the 2,6-diaminopyridine scaffold were studied as homogeneous, non-precious-metal-based catalysts for selective formic acid dehydrogenation to hydrogen and carbon dioxide, reaching quantitative yields and high TONs under mild reaction conditions.File in questo prodotto:
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Descrizione: Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold
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Descrizione: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, copyright © 2016 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.organomet.6b00551.
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