Archaeological wood, as most of natural materials, is slowly decomposing on the archaeological site due to various biological factors. Rapid and accurate estimation of the degradation level is extremely important for optimal restoration and conservation. The goal of this research was to verify the effectiveness of Fourier transform near infrared (FT-NIR) spectroscopy for archaeometry. The important advantage of the NIR spectroscopy is its accuracy, simplicity and ability to perform very high number of tests without needs of any destruction to the workpiece. Five oak pieces of the archaeological wood collected from waterlogged sites in Poland have been used. Cellulose and lignin contents, as well as crystallinity and the degree of polymerization were measured with standard reference methods and compared to the contemporary wood. The near infrared spectra represent all the physical/chemical changes of the wood due to waterlogging. This technique was successfully validated in rapid estimation of the cellulose and lignin contents. The method explored in this research might be a novel tool assisting experts in evaluation of the degradation state of archaeological and historical wooden materials.
Near infrared spectroscopy as a tool for archaeological wood characterization
Sandak A;Sandak J;
2010
Abstract
Archaeological wood, as most of natural materials, is slowly decomposing on the archaeological site due to various biological factors. Rapid and accurate estimation of the degradation level is extremely important for optimal restoration and conservation. The goal of this research was to verify the effectiveness of Fourier transform near infrared (FT-NIR) spectroscopy for archaeometry. The important advantage of the NIR spectroscopy is its accuracy, simplicity and ability to perform very high number of tests without needs of any destruction to the workpiece. Five oak pieces of the archaeological wood collected from waterlogged sites in Poland have been used. Cellulose and lignin contents, as well as crystallinity and the degree of polymerization were measured with standard reference methods and compared to the contemporary wood. The near infrared spectra represent all the physical/chemical changes of the wood due to waterlogging. This technique was successfully validated in rapid estimation of the cellulose and lignin contents. The method explored in this research might be a novel tool assisting experts in evaluation of the degradation state of archaeological and historical wooden materials.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
