The photodegradation of 6'-indolino-1-isobutyl-3,3-dimethylspiro[indoline-2,3'-[3H]naphtho[2,1-b][1,4]oxazine] (1) following exposure to polychromatic light, was investigated in fluid solution (toluene, T) and in a solid matrix (polyurethane, PU). The photoproducts formed under irradiation were identified using HPLC and GC/MS. These included, beside the expected degradation derivatives, some new photoproducts derived from a secondary degradation pathway.

A Special Focus on the Photodegradation of 6 '-Indolino-1-isobutyl-3,3-dimethylspiro[indoline-2,3 '-[3H]naphtho[2,1-b][1,4]oxazine]

Alberti Angelo;
2012

Abstract

The photodegradation of 6'-indolino-1-isobutyl-3,3-dimethylspiro[indoline-2,3'-[3H]naphtho[2,1-b][1,4]oxazine] (1) following exposure to polychromatic light, was investigated in fluid solution (toluene, T) and in a solid matrix (polyurethane, PU). The photoproducts formed under irradiation were identified using HPLC and GC/MS. These included, beside the expected degradation derivatives, some new photoproducts derived from a secondary degradation pathway.
2012
Istituto per la Sintesi Organica e la Fotoreattivita' - ISOF
SPECTROSCOPIC CHARACTERIZATION; PHOTOCHROMIC COMPOUNDS; DERIVATIVES; INDOLINOSPIROPYRANS; SPIROOXAZINES; SPIROPYRANS; PHOTOLYSIS
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/314796
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