Ce0.15Zr0.85O2 was investigated in the two-step water splitting reaction. High-temperature treatment in N-2 induced compositional and structural heterogeneities which contributed to a six-fold increase of H-2 yield after the first cycle. Ceria surface enrichment and the formation of a ceria-zirconia oxynitride phase positively affected the reduction and oxidation steps.

Water splitting reaction on Ce0.15Zr0.85O2 driven by surface heterogeneity

Armelao L;
2016

Abstract

Ce0.15Zr0.85O2 was investigated in the two-step water splitting reaction. High-temperature treatment in N-2 induced compositional and structural heterogeneities which contributed to a six-fold increase of H-2 yield after the first cycle. Ceria surface enrichment and the formation of a ceria-zirconia oxynitride phase positively affected the reduction and oxidation steps.
2016
Istituto di Chimica della Materia Condensata e di Tecnologie per l'Energia - ICMATE
water splitting
surface
XPS
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/314904
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