NMR-spectroscopic studies of V-51, Mo-95, Co-59, O-17, and H-1 nuclei present in coordination compounds that catalyze alkene and alkane oxidation with organic hydroperoxides are reviewed. Multinuclear NMR spectroscopy was shown to have advantages in structural studies of selective oxidation intermediates.
Structure of Mo(VI), V(V), and Ti(IV) alkylperoxy and peroxy complexes deduced from NMR data and their reactivity
1997
Abstract
NMR-spectroscopic studies of V-51, Mo-95, Co-59, O-17, and H-1 nuclei present in coordination compounds that catalyze alkene and alkane oxidation with organic hydroperoxides are reviewed. Multinuclear NMR spectroscopy was shown to have advantages in structural studies of selective oxidation intermediates.File in questo prodotto:
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