The mechanism of formation of Pt@SiO2 as a model of core-shell nanoparticles via water-in-oil reverse microemulsions was studied in detail. By controlling the time of growth of Pt precursors, Pt(OH)(x), after hydrolysis in NH3 aq. before adding SiO2 precursor (TEOS), Pt nanoparticles with a narrow size distribution were produced, from ultrafine metal nanoparticles (<1 nm) to 6 nm nanocrystals. Separately, the thickness of SiO2 was controllably synthesized from 1 to 15 nm to yield different Pt@SiO2 materials. The Pt@SiO2 core-shell catalysts exhibited a higher rate of CO oxidation by one order of magnitude with a positive order regarding CO pressure. The SiO2 shell did not perturb the Pt chemical nature, but it provided different coverage of CO in steady-state CO oxidation. (C) 2016 Elsevier Inc. All rights reserved.
Design of a core-shell Pt-SiO2 catalyst in a reverse microemulsion system: Distinctive kinetics on CO oxidation at low temperature
Fornasiero Paolo;
2016
Abstract
The mechanism of formation of Pt@SiO2 as a model of core-shell nanoparticles via water-in-oil reverse microemulsions was studied in detail. By controlling the time of growth of Pt precursors, Pt(OH)(x), after hydrolysis in NH3 aq. before adding SiO2 precursor (TEOS), Pt nanoparticles with a narrow size distribution were produced, from ultrafine metal nanoparticles (<1 nm) to 6 nm nanocrystals. Separately, the thickness of SiO2 was controllably synthesized from 1 to 15 nm to yield different Pt@SiO2 materials. The Pt@SiO2 core-shell catalysts exhibited a higher rate of CO oxidation by one order of magnitude with a positive order regarding CO pressure. The SiO2 shell did not perturb the Pt chemical nature, but it provided different coverage of CO in steady-state CO oxidation. (C) 2016 Elsevier Inc. All rights reserved.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
