The nature of the emitting states and their geometric distortions relative to the ground states in [Au3L2](3+) and [Au2L2](2+) was studied by DFT, revealing contraction of the AuAu distances and coordination geometry changes by association of the dangling P donor, respectively.
Bonding, Luminescence, Metallophilicity in Linear Au-3 and Au2Ag Chains Stabilized by Rigid Diphosphanyl NHC Ligands
Giovanella Umberto;Botta Chiara;
2016
Abstract
The nature of the emitting states and their geometric distortions relative to the ground states in [Au3L2](3+) and [Au2L2](2+) was studied by DFT, revealing contraction of the AuAu distances and coordination geometry changes by association of the dangling P donor, respectively.File in questo prodotto:
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Descrizione: Bonding, Luminescence, Metallophilicity in Linear Au3 and Au2Ag Chains Stabilized by Rigid Diphosphanyl NHC Ligands
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