We report the evolution of structural, dielectric, ferroelectric and ferromagnetic properties in novel (Pb1 - 3x/2Ndx)(Ti0.98 - yFeyMn0.02)O3 perovskite ceramics(x = 0.08, 0 < y < 0.05). We found room-temperature ferroelectric polarization and ferromagnetism for higher amount of iron ions(y = 0.04). The paraelectric-ferroelectric phase transition occurred between 650 and 670 K for 0 = y = 0.05. Ferromagnetic hysteresis was measured at different temperatures on samples with y = 0.04. Detailed structural analysis evidenced the variation of unit cell parameters with y increasing, confirming the substitution of the iron element in the lattice. 57Fe Mössbauer spectroscopy evidenced that iron ions occupy Ti positions in the perovskite lattice, with the oxidation state Fe3 + and two coordination types. X-ray photoelectron spectroscopy confirmed the presence of iron only as Fe3 + and, moreover, evidenced the presence of a substantial amount of Ti3 + ions in the structure. The presence of both Fe3 + (spin 5/2) in different coordinations as well as Ti3 + (spin 1/2) magnetic ions in B-site positions drives the occurrence of magnetic properties from low temperature to above room temperature, through superexchange Fe3 +-O-Fe3 +, Fe3 +-O-Ti3 + and Ti3 +-O-Ti3 + interactions. The finding of coexistent ferroelectric and ferromagnetic properties in these compounds ground the route to facile synthesis of multiferroics by simply doping a classical perovskite ferroelectric material like PbTiO3 with an adequate amount of transition magnetic ions.
Novel multiferroic (Pb1 - 3x/2Ndx)(Ti0.98 - yFeyMn0.02)O3 ceramics with coexisting ferroelectricity and ferromagnetism at ambient temperature
C Galassi
2016
Abstract
We report the evolution of structural, dielectric, ferroelectric and ferromagnetic properties in novel (Pb1 - 3x/2Ndx)(Ti0.98 - yFeyMn0.02)O3 perovskite ceramics(x = 0.08, 0 < y < 0.05). We found room-temperature ferroelectric polarization and ferromagnetism for higher amount of iron ions(y = 0.04). The paraelectric-ferroelectric phase transition occurred between 650 and 670 K for 0 = y = 0.05. Ferromagnetic hysteresis was measured at different temperatures on samples with y = 0.04. Detailed structural analysis evidenced the variation of unit cell parameters with y increasing, confirming the substitution of the iron element in the lattice. 57Fe Mössbauer spectroscopy evidenced that iron ions occupy Ti positions in the perovskite lattice, with the oxidation state Fe3 + and two coordination types. X-ray photoelectron spectroscopy confirmed the presence of iron only as Fe3 + and, moreover, evidenced the presence of a substantial amount of Ti3 + ions in the structure. The presence of both Fe3 + (spin 5/2) in different coordinations as well as Ti3 + (spin 1/2) magnetic ions in B-site positions drives the occurrence of magnetic properties from low temperature to above room temperature, through superexchange Fe3 +-O-Fe3 +, Fe3 +-O-Ti3 + and Ti3 +-O-Ti3 + interactions. The finding of coexistent ferroelectric and ferromagnetic properties in these compounds ground the route to facile synthesis of multiferroics by simply doping a classical perovskite ferroelectric material like PbTiO3 with an adequate amount of transition magnetic ions.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.