Hetero Diels-Alder reaction between 2-aza-3-trimethylsilyloxy-1,3-diene and aldehydes gives rise to tetrahydrooxazin-4-ones, useful intermediates in the synthesis of alpha-amino-beta-hydroxy acids. Herein we report the complete stereoselective synthesis of D-serine Cbz-methyl ester.
Enanthioselective synthesis of protected D-serine from tetrahydrooxazin-4-one via hetero Diels-Alder reaction
2002
Abstract
Hetero Diels-Alder reaction between 2-aza-3-trimethylsilyloxy-1,3-diene and aldehydes gives rise to tetrahydrooxazin-4-ones, useful intermediates in the synthesis of alpha-amino-beta-hydroxy acids. Herein we report the complete stereoselective synthesis of D-serine Cbz-methyl ester.File in questo prodotto:
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