Unusual temperature-dependent linewidth variations were observed in spin adducts of (dimenthoxy)phosphoryl methyl dithioformate with bulky free radicals, possibly involving a combination of restricted rotation of a methyl group and slow molecular tumbling.

Phosphoryldithioformates: Part V. Unusual Linewidth Variations in the ESR Spectra of Some Spin Adducts of (Dimethoxy)phosphoryl Methyl Dithioformates

A Alberti;M Benaglia;D Macciantelli;
2002

Abstract

Unusual temperature-dependent linewidth variations were observed in spin adducts of (dimenthoxy)phosphoryl methyl dithioformate with bulky free radicals, possibly involving a combination of restricted rotation of a methyl group and slow molecular tumbling.
2002
Istituto per la Sintesi Organica e la Fotoreattivita' - ISOF
(dimenthoxy)phosphorylmethyldithioformate; formic acid derivative; free radical; methyl group; unclassified drug;chemical analysis; electron spin resonance; rotation; temperature dependence
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/32170
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 4
  • ???jsp.display-item.citation.isi??? ND
social impact