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Unusual temperature-dependent linewidth variations were observed in spin adducts of (dimenthoxy)phosphoryl methyl dithioformate with bulky free radicals, possibly involving a combination of restricted rotation of a methyl group and slow molecular tumbling.

Phosphoryldithioformates: Part V. Unusual Linewidth Variations in the ESR Spectra of Some Spin Adducts of (Dimethoxy)phosphoryl Methyl Dithioformates

A Alberti;M Benaglia;D Macciantelli;
2002

Abstract

Unusual temperature-dependent linewidth variations were observed in spin adducts of (dimenthoxy)phosphoryl methyl dithioformate with bulky free radicals, possibly involving a combination of restricted rotation of a methyl group and slow molecular tumbling.
2002
Istituto per la Sintesi Organica e la Fotoreattivita' - ISOF
Inglese
WOS:000175746300002
40
6
387
390
4
2-s2.0-0005047228
Sì, ma tipo non specificato
(dimenthoxy)phosphorylmethyldithioformate; formic acid derivative; free radical; methyl group; unclassified drug;chemical analysis; electron spin resonance; rotation; temperature dependence
5
info:eu-repo/semantics/article
262
Alberti, A; Benaglia, M; Macciantelli, D; Hudson, A; Masson, M
01 Contributo su Rivista::01.01 Articolo in rivista
none
01.01 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/32170
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