This review is a comprehensive survey of the last ten years research on ammonia-borane and amine-boranes dehydrogenation mediated by complex metal hydrides (CMHs), within the broader context of chemical hydrogen storage. The manuscript also collects those cases where CMHs are the catalyst spent form or its resting state. Highlights on the reaction mechanism (strictly dependent from the CMH of choice) and the catalysts efficiency (in terms of equivalents of H2 produced and relative reaction rates) are provided throughout the discussion.
Ammonia-Borane and Amine-Borane Dehydrogenation Mediated by Complex Metal Hydrides
Rossin Andrea;Peruzzini Maurizio
2016
Abstract
This review is a comprehensive survey of the last ten years research on ammonia-borane and amine-boranes dehydrogenation mediated by complex metal hydrides (CMHs), within the broader context of chemical hydrogen storage. The manuscript also collects those cases where CMHs are the catalyst spent form or its resting state. Highlights on the reaction mechanism (strictly dependent from the CMH of choice) and the catalysts efficiency (in terms of equivalents of H2 produced and relative reaction rates) are provided throughout the discussion.File in questo prodotto:
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