Fe(II) hydrido carbonyl complexes supported by PNP pincer ligands based on the 2,6-diaminopyridine scaffold were found to promote the catalytic hydrogenation of CO2 and NaHCO3 to formate in protic solvents in the presence of bases, reaching quantitative yields and high TONs under mild reaction conditions, with pressures as low as 8.5 bar and temperatures as low as 25 °C. NMR and DFT studies highlighted the role of dihydrido and hydrido formate complexes in catalysis.
Efficient and Mild Carbon Dioxide Hydrogenation to Formate Catalyzed by Fe(II) Hydrido Carbonyl Complexes Bearing 2,6-(Diaminopyridyl)diphosphine Pincer Ligands
Bertini, Federica;Peruzzini, Maurizio;Gonsalvi, Luca
2016
Abstract
Fe(II) hydrido carbonyl complexes supported by PNP pincer ligands based on the 2,6-diaminopyridine scaffold were found to promote the catalytic hydrogenation of CO2 and NaHCO3 to formate in protic solvents in the presence of bases, reaching quantitative yields and high TONs under mild reaction conditions, with pressures as low as 8.5 bar and temperatures as low as 25 °C. NMR and DFT studies highlighted the role of dihydrido and hydrido formate complexes in catalysis.File in questo prodotto:
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Descrizione: Efficient and Mild Carbon Dioxide Hydrogenation to Formate Catalyzed by Fe(II) Hydrido Carbonyl Complexes...
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cs-2016-00416s revised final.pdf
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Descrizione: This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © 2016 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see ttps://doi.org/10.1021/acscatal.6b00416."
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