The National Institute of Standards and Technology (NIST) database on ionization potentials for neutral atoms and ions is examined. For each isoelectronic sequence, we construct a regularized perturbative series based on the large-Z (heavy cations) and Z ? N - 1 (singly charged anion) behaviors. Comparison of the NIST data with this series allows the identification of problematic values in the reported data.

The NIST compilation of ionization potentials revisited (I): From He-like to Xe-like ions

2017

Abstract

The National Institute of Standards and Technology (NIST) database on ionization potentials for neutral atoms and ions is examined. For each isoelectronic sequence, we construct a regularized perturbative series based on the large-Z (heavy cations) and Z ? N - 1 (singly charged anion) behaviors. Comparison of the NIST data with this series allows the identification of problematic values in the reported data.
2017
Istituto Nanoscienze - NANO
Atomic ions
Ionization potential
Large-Z expansion
NIST atomic spectra database
Regularized perturbation theory
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/325954
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