A process for the one-step transformation of butanol into butyl butyrate has been set up by using a copper/zirconia catalyst. Yields of up to 98% can be obtained at 250 degrees C by withdrawing the H-2 formed. The high activity has been investigated through STEM analysis of the catalyst and FT IR spectroscopy of the substrate adsorbed on the catalyst surface.
Dehydrogenative coupling promoted by copper catalysts: a way to optimise and upgrade bioalcohols
Scotti Nicola;Zaccheria Federica;Evangelisti Claudio;Psaro Rinaldo;
2017
Abstract
A process for the one-step transformation of butanol into butyl butyrate has been set up by using a copper/zirconia catalyst. Yields of up to 98% can be obtained at 250 degrees C by withdrawing the H-2 formed. The high activity has been investigated through STEM analysis of the catalyst and FT IR spectroscopy of the substrate adsorbed on the catalyst surface.File in questo prodotto:
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Descrizione: Dehydrogenative coupling promoted by copper catalysts: a way to optimise and upgrade bioalcohols
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