The capability of propolis wax, beeswax and their mixture to gel pomegranate seed oil (PSO) was studied. Samples were prepared increasing the concentration of waxes in pomegranate seed oil from 5 to 15% (w/w). After propolis wax, beeswax and PSO chemical characterization, t hermal and structural properties of wax - based organogels were studied. Both propolis wax and beeswax formed organogel thanks to the presence of crystal networks made of needle- like ?? -form crystals. Based on FTIR spectroscopy, mainly van der Waals interact ions were formed in the systems. Propolis wax organogels displayed lower firmness and G ? and G ? ? modulus in comparison to the corresponding beeswax samples. This was due to the presence of larger crystals with a less organized network. The observed behaviors were attributed to differences in chemical composition between these two types of waxes. The combined use of propolis wax and beeswax led to organogels with behavior in between the organogels with single waxes, probably as a consequence of the formation of mixed crystals.
Pomegranate seed oil organogels structured by propolis wax, beeswax and their mixture
2017
Abstract
The capability of propolis wax, beeswax and their mixture to gel pomegranate seed oil (PSO) was studied. Samples were prepared increasing the concentration of waxes in pomegranate seed oil from 5 to 15% (w/w). After propolis wax, beeswax and PSO chemical characterization, t hermal and structural properties of wax - based organogels were studied. Both propolis wax and beeswax formed organogel thanks to the presence of crystal networks made of needle- like ?? -form crystals. Based on FTIR spectroscopy, mainly van der Waals interact ions were formed in the systems. Propolis wax organogels displayed lower firmness and G ? and G ? ? modulus in comparison to the corresponding beeswax samples. This was due to the presence of larger crystals with a less organized network. The observed behaviors were attributed to differences in chemical composition between these two types of waxes. The combined use of propolis wax and beeswax led to organogels with behavior in between the organogels with single waxes, probably as a consequence of the formation of mixed crystals.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.


