Measurements by capillary pressure tensiometry, under microgravity conditions aboard the International Space Station, supplied a consistent set of reliable results for the dynamic interfacial tension and for the interfacial dilational viscoelastic modulus, quantitatively characterizing the dynamics of Span-80 adsorbed layers at the paraffin-oil/water interface.The experiments were executed at three different temperatures, i.e., 20, 30 and 40 degrees C, according to a preestablished built-in time-line in the orbiting facility. The interfacial area was subjected to perturbations with various functional forms (square pulses, ramps and harmonic oscillations), at three consecutive amplitudes (5%, 10% and 20%). Each experiment was performed in three successive repetitions, in view of an advantageous telemetered data redundancy.

Dynamic properties of Span-80 adsorbed layers at paraffin-oil/water interface: Capillary pressure experiments under low gravity conditions

Loglio G;Ravera F;Liggieri L;
2017

Abstract

Measurements by capillary pressure tensiometry, under microgravity conditions aboard the International Space Station, supplied a consistent set of reliable results for the dynamic interfacial tension and for the interfacial dilational viscoelastic modulus, quantitatively characterizing the dynamics of Span-80 adsorbed layers at the paraffin-oil/water interface.The experiments were executed at three different temperatures, i.e., 20, 30 and 40 degrees C, according to a preestablished built-in time-line in the orbiting facility. The interfacial area was subjected to perturbations with various functional forms (square pulses, ramps and harmonic oscillations), at three consecutive amplitudes (5%, 10% and 20%). Each experiment was performed in three successive repetitions, in view of an advantageous telemetered data redundancy.
2017
Istituto di Chimica della Materia Condensata e di Tecnologie per l'Energia - ICMATE
Inglese
532
228
243
16
http://www.sciencedirect.com/science/article/pii/S092777571730434X
Sì, ma tipo non specificato
Water/paraffin-oil interface
Span-80
Sorbitan monooleate
Adsorption layer
Dynamic interfacial tension
Interfacial dilational viscoelasticity
Diffusion-controlled adsorption
Highlights o Measurements by capillary pressure tensiometry, under microgravity conditions, are effective for providing a consistent set of reliable data for the dynamic properties of a liquid/liquid interface. o The hydrocarbon/water interface exhibits a viscoelastic behavior, which is measured by the value of the interfacial dilational modulus as a function of frequency. o Responses to harmonic interfacial perturbations manifest diffusional bulk-interface transport (i.e., diffusion-controlled adsorption). o An acceptable linearity range exists for the interfacial responses to area perturbations up to 20% amplitude, as assessed by the total harmonic distortion parameter. o Oscillations in the high-frequency range satisfactorily describe the system dynamics.
11
info:eu-repo/semantics/article
262
Pandolfini, P; Loglio, G; Ravera, F; Liggieri, L; Kovalchuk, V I; Javadi, A; Karbaschi, M; Kraegel, J; Miller, R; Noskov, B A; Bykov, A G
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/332099
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