The oxidative addition of chloro-, bromo-and iodobenzene to the cationic bis(phosphane)rhodium complex [Rh(DIPAMP)(MeOH)(2)]BF4 was investigated. The resulting complexes were characterized by X-ray analysis and NMR spectroscopy and applied as catalysts in classical cross-coupling reactions. Product inhibition was observed and quantified by UV/Vis and NMR spectroscopy.

Oxidative Addition of Aryl Halides to Cationic Bis(phosphane)rhodium Complexes: Application in C-C Bond Formation

Alberico Elisabetta;
2017

Abstract

The oxidative addition of chloro-, bromo-and iodobenzene to the cationic bis(phosphane)rhodium complex [Rh(DIPAMP)(MeOH)(2)]BF4 was investigated. The resulting complexes were characterized by X-ray analysis and NMR spectroscopy and applied as catalysts in classical cross-coupling reactions. Product inhibition was observed and quantified by UV/Vis and NMR spectroscopy.
2017
Istituto di Chimica Biomolecolare - ICB - Sede Pozzuoli
Oxidative addition
Rhodium
UV/Vis spectroscopy
C-C coupling
Product inhibition
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/332933
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