2,2'-bipyridine end-functionalized Pd-PEG macrocomplexs were synthesized by a molecular approach and used to access Pd-nanoparticles stabilized by the nitrogen donor atoms of the polymer. The water soluble Pd-nanopartricles were successfully applied to hydrate nitriles to the corresponding amide in neat water.
Water-soluble nanostructured palladium catalysts: synthesis, characterization and application for nitrile hydrolysis
Oberhauser Werner;Passaglia Elisa;
2017
Abstract
2,2'-bipyridine end-functionalized Pd-PEG macrocomplexs were synthesized by a molecular approach and used to access Pd-nanoparticles stabilized by the nitrogen donor atoms of the polymer. The water soluble Pd-nanopartricles were successfully applied to hydrate nitriles to the corresponding amide in neat water.File in questo prodotto:
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