Biodegradable thermoplastic gelatin/poly(butylene succinate) (TPG/PBS) foams were prepared by melt mixing and subsequent batch foaming with supercritical CO<inf>2</inf>. Shear viscosity and calorimetric properties of the various blends were investigated using a rotational rheometer and a differential scanning calorimeter, respectively. TPG/PBS blends show poor miscibility at all blend ratios. The addition of PBS reduced the melt viscosity and increased both the CO<inf>2</inf> diffusivity and the thermal stability of TPG. Results from foaming experiments show that the blend foams exhibit smaller cell size and higher cell density compared to the neat TPG foam due to the lower melt viscosity and to their lower gas barrier.
Foaming behavior of bio-based blends based on thermoplastic gelatin and poly(butylene succinate)
Oliviero Maria;Sorrentino Luigi;Cafiero Livia;Sorrentino Andrea;Iannace Salvatore
2015
Abstract
Biodegradable thermoplastic gelatin/poly(butylene succinate) (TPG/PBS) foams were prepared by melt mixing and subsequent batch foaming with supercritical COI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.