A novel technique, named longitudinally modulated electron nuclear double resonance (LOMENDOR), is reported. The lineshape of the signal is studied as a function of the relaxation times of the spin system under study and as a function of the microwave and radiofrequency field strengths. Analytical expressions of the line intensity and width are obtained at low saturation factors. The experimental setup is described and the results are compared with theory. The application of LOMENDOR for the direct measurement of relaxation times is discussed in detail. © 1989.
Longitudinally modulated ENDOR spectroscopy. Lineshape and signal dependence on relaxation times
Pinzino C
1989
Abstract
A novel technique, named longitudinally modulated electron nuclear double resonance (LOMENDOR), is reported. The lineshape of the signal is studied as a function of the relaxation times of the spin system under study and as a function of the microwave and radiofrequency field strengths. Analytical expressions of the line intensity and width are obtained at low saturation factors. The experimental setup is described and the results are compared with theory. The application of LOMENDOR for the direct measurement of relaxation times is discussed in detail. © 1989.File in questo prodotto:
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