Whether in supercritical CO2 or in organic solvent and using O2 or aqueous H2 O2 as primary oxidants, the series of sol-gel entrapped TPAP hybrid silica gels is a versatile class of oxidation catalysts suitable for the highly selective conversion of alcohols to carbonyls. These materials are generally more stable and active than traditional polymer-supported analogues. This report summarizes recent findings showing the large potential of this technology for synthetic chemistry.
Sol-gel entrapped TPAP: An off-the-shelf catalyst set for the clean oxidation of alcohols
Rosaria Ciriminna;Mario Pagliaro
2008
Abstract
Whether in supercritical CO2 or in organic solvent and using O2 or aqueous H2 O2 as primary oxidants, the series of sol-gel entrapped TPAP hybrid silica gels is a versatile class of oxidation catalysts suitable for the highly selective conversion of alcohols to carbonyls. These materials are generally more stable and active than traditional polymer-supported analogues. This report summarizes recent findings showing the large potential of this technology for synthetic chemistry.File in questo prodotto:
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